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one of my favourite sites is
all-guitar-chords.com
even tho it's a guitar site, you can use it to apply to some other areas of music; if you know your chords, scales on other instruments.
A major does not correctly fit into the E natural minor scale.
If you look at all the notes that produces the E minor scale its:
E, F#, G, A, B, C, D
These are always the notes that are used to form chords with in the E Natural Minor scale. A MAJOR uses a C# as it's third.
Realize, the relative major of E Minor is G - Major! If you use G as your tonic or root note and start you progression with G Major instead of E minor , your song will have a much more lifted feel to it.
Of course there are always little exceptions that are super deep into theory. For instance, Beethoven's Fur Elise is technically composed in C Major, but it has sooo many accents in it that it basically uses every note possible. LOL
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