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FWIW, my dad, who was in the plastics industry for 20+ years (sales & marketing, not engineering, so you should take this with a big grain of salt) insists that closed-cell expanded polystyrene foam insulation -- the stuff that (often incorrectly) gets referred to as Styrofoam® -- does exhibit some soundproofing properties when used as the middle layer in a sandwich between sheetrock and/or plywood leaves.
He suspects that due to the the irregular, non-uniform shape of the expanded plastic beads, as well as perhaps the compliant nature of the material, sound transmission is impeded through the EPS board.
I can think of plenty of reasons why it would be preferable to use RockWool (or the equivalent) rather than EPS...but I guess I can also see how EPS could fulfill certain requirements both acoustical and environmental.
It's definitely *not* commonly used for its sonic properties.
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